`a)PTHH:`

`2Al + 3H_2 SO_4 -> Al_2(SO_4)_3 + 3H_2 \uparrow`

  `2`           `3`                      `1`             `3`                 `(mol)`

`b)n_[H_2 SO_4]=[300.98]/[100.98]=3(mol)`

  `m_[Al]=2.27=54(g)`

  `m_[Al_2(SO_4)_3=1.342=342(g)`

  `V_[H_2]=3.22,4=67,2(l)`

  hơi khó thấy thì bn bình luận dưới đây nhé!

2Al+3H2SO4->Al2(SO4)3+3H2

0,1----------------------0,075----0,15

n H2=0,15 mol

=>mAl=0,1.27=2,7g

=>m Al2(SO4)3=0,075.342=25,65g

a) PTHH: \(2Al+3H_2SO_2\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

b) \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

\(n_{Al}=\dfrac{2}{3}.0,15=0,1\left(mol\right)\)

\(m_{Al}=0,1.27=2,7\left(g\right)\)

c) \(n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}.0,1=0,05\left(mol\right)\)

\(m_{Al_2\left(SO_4\right)_3}=0,05.342=17,1\left(g\right)\)

2Al+3H2SO4->Al2(SO4)3+3H2

0,1----------------------0,075----0,15

n H2=0,15 mol

=>mAl=0,1.27=2,7g

=>m Al2(SO4)3=0,075.342=25,65g

a) Gọi \(\left\{{}\begin{matrix}n_{Fe}=a\left(mol\right)\\n_{Zn}=b\left(mol\right)\end{matrix}\right.\) \(\Rightarrow56a+65b=12,1\)  (1)

Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

Bảo toàn electron: \(2n_{Fe}+2n_{Zn}=2n_{H_2}\) \(\Rightarrow2a+2b=0,4\)  (2)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,1\cdot56}{12,1}\cdot100\%\approx46,28\%\\\%m_{Zn}=53,72\%\end{matrix}\right.\)

b)

Bảo toàn nguyên tố: \(\left\{{}\begin{matrix}n_{FeSO_4}=n_{Fe}=n_{Zn}=n_{ZnSO_4}=0,1\left(mol\right)\\n_{H_2SO_4\left(p.ứ\right)}=n_{H_2}=0,2\left(mol\right)\Rightarrow\Sigma n_{H_2SO_4}=0,2\cdot110\%=0,22\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{FeSO_4}=0,1\cdot152=15,2\left(g\right)\\m_{ZnSO_4}=0,1\cdot161=16,1\left(g\right)\\m_{H_2}=0,2\cdot2=0,4\left(g\right)\\m_{H_2SO_4\left(dư\right)}=\left(0,22-0,2\right)\cdot98=1,96\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd}=m_{KL}+m_{ddH_2SO_4}-m_{H_2}=211,7\left(g\right)\)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{FeSO_4}=\dfrac{15,2}{211,7}\cdot100\%\approx7,18\%\\C\%_{ZnSO_4}=\dfrac{16,1}{211,7}\cdot100\%\approx7,61\%\\C\%_{H_2SO_4}=\dfrac{1,96}{22,4}\cdot100\%\approx0,93\%\end{matrix}\right.\)

PT: \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

\(Cu+2H_2SO_{4\left(đ\right)}\underrightarrow{t^o}CuSO_4+SO_2+2H_2O\)

Ta có: \(n_{SO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)

Theo PT: \(n_{Cu}=n_{SO_2}=0,25\left(mol\right)\)

\(\Rightarrow\%m_{Cu}=\dfrac{0,25.64}{24}.100\%\approx66,67\%\)

Chỉ có Zn phản ứng thôi. Cu không phản ứng, không tan.---->Chất rắn không tan là Cu

Zn+ H2SO4 ---> ZnSO4+ H2↑
0.1 0.1
nH2= 2.24: 22.4=0.1 mol
mZn= 0.1x65=6.5 g
mCu=10.5-6,5=4 g
%Zn=6.5:10.5x100%=61.9%
%Cu=4:10.5x100%=38.1%

Ta có: \(m_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\) \(\Rightarrow m_{H_2}=0,2\cdot2=0,4\left(g\right)\)

\(\Rightarrow m_{dd\left(sau.pư\right)}=m_{hh}+m_{ddH_2SO_4}-m_{H_2}=309,6\left(g\right)\)

\(\Rightarrow a=309,6-300=9,6\left(g\right)\)

đề ko cho nồng độ phần trăm của dd H₂SO₄ à

Đáp án C

Chọn C.

2,4.